Sodium Thiosulfate

Sodium thiosulfate, also spelled sodium thiosulphate, is a colorless crystalline compound that is more familiar as the pentahydrate, Na2S2O3o5H2O, an efflorescent, monoclinic crystalline substance also called sodium hyposulfite or "hypo. " The thiosulfate anion is tetrahedral in shape and is notionally derived by replacing one of the oxygen atoms by a sulfur atom in a sulfate anion. The S-S distance indicates a single bond, implying that the sulfur bears significant negative charge and the S-O interactions have more double bond character. The first protonation of thiosulfate occurs at sulfur.

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